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Ir[dFppy]2(dtbbpy)PF6

Ir[dFppy]2(dtbbpy)PF6 Structure
  • ₹13841.7
  • Product name: Ir[dFppy]2(dtbbpy)PF6
  • CAS: 1072067-44-7
  • MF: C40H36F10IrN4P
  • MW: 985.93
  • EINECS:
  • MDL Number:MFCD31657504
  • Synonyms:Ir[dFppy]2(dtbbpy)PF6;[2,2'-bis (4-tert-butylpyridine)] bis [2- (2,4-difluorophenyl) pyridine] iridium (III) hexafluorophosphate;C]iridium hexafluorophosphate, 97%;(Ir[dFppy]2(dtbpy))PF6;[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate, 97%;[4,4'-Bis(1,1-dimethyL;-κC]iridium hexafL;)-2,2'-bipyridine-κN,κN]bis[3,5-difL
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Brand

  • Sigma-Aldrich(India)

Package

  • 100MG
  • ManufacturerSigma-Aldrich(India)
  • Product number901368
  • Product description[Ir(dFppy)2(dtbbpy)]PF6
  • Packaging100MG
  • Price₹13841.7
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 901368 [Ir(dFppy)2(dtbbpy)]PF6 100MG ₹13841.7 2022-06-14 Buy

Properties

Melting point :>300°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :powder or crystals

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.

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